Formation Constants for Complex Ions

Klaus Theopold; Paul Flowers; Richard Langley; William R. Robinson

Formation Constants for Complex Ions

Formation Constants for Complex Ions
Equilibrium	K_f
${\text{Al}}^{\text{3+}}+6{\text{F}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[{\text{AlF}}_{6}\right]}^{\text{3−}}$	7 $×$ 10¹⁹
${\text{Cd}}^{\text{2+}}+4{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Cd}{\left({\text{NH}}_{3}\right)}_{4}\right]}^{\text{2}\text{+}}$	1.3 $×$ 10⁷
${\text{Cd}}^{\text{2+}}+4{\text{CN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Cd}{\left(\text{CN}\right)}_{4}\right]}^{2-}$	3 $×$ 10¹⁸
${\text{Co}}^{\text{2+}}+6{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Co}{\left({\text{NH}}_{3}\right)}_{6}\right]}^{2+}$	1.3 $×$ 10⁵
${\text{Co}}^{\text{3+}}+6{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Co}{\left({\text{NH}}_{3}\right)}_{6}\right]}^{3+}$	2.3 $×$ 10³³
${\text{Cu}}^{+}+2\text{CN}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Cu}{\left(\text{CN}\right)}_{2}\right]}^{-}$	1.0 $×$ 10¹⁶
${\text{Cu}}^{\text{2+}}+4{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Cu}{\left({\text{NH}}_{3}\right)}_{4}\right]}^{2+}$	1.7 $×$ 10¹³
${\text{Fe}}^{\text{2+}}+6{\text{CN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Fe}{\left(\text{CN}\right)}_{6}\right]}^{4-}$	1.5 $×$ 10³⁵
${\text{Fe}}^{\text{3+}}+6{\text{CN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Fe}{\left(\text{CN}\right)}_{6}\right]}^{3-}$	2 $×$ 10⁴³
${\text{Fe}}^{\text{3+}}+6{\text{SCN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Fe}{\left(\text{SCN}\right)}_{6}\right]}^{3-}$	3.2 $×$ 10³
${\text{Hg}}^{\text{2+}}+4{\text{Cl}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[{\text{HgCl}}_{4}\right]}^{2-}$	1.1 $×$ 10¹⁶
${\text{Ni}}^{\text{2+}}+6{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Ni}{\left({\text{NH}}_{3}\right)}_{6}\right]}^{2+}$	2.0 $×$ 10⁸
${\text{Ag}}^{\text{+}}+2{\text{Cl}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[{\text{AgCl}}_{2}\right]}^{-}$	1.8 $×$ 10⁵
${\text{Ag}}^{\text{+}}+2{\text{CN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Ag}{\left(\text{CN}\right)}_{2}\right]}^{-}$	1 $×$ 10²¹
${\text{Ag}}^{\text{+}}+2{\text{NH}}_{\text{3}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Ag}{\left({\text{NH}}_{3}\right)}_{2}\right]}^{+}$	1.7 $×$ 10⁷
${\text{Zn}}^{\text{2+}}+4{\text{CN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Zn}{\left(\text{CN}\right)}_{4}\right]}^{2-}$	2.1 $×$ 10¹⁹
${\text{Zn}}^{\text{2+}}+4{\text{OH}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Zn}{\left(\text{OH}\right)}_{4}\right]}^{2-}$	2 $×$ 10¹⁵
${\text{Fe}}^{\text{3+}}+{\text{SCN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Fe}\left(\text{SCN}\right)\right]}^{2+}$	8.9 $×$ 10²
${\text{Ag}}^{\text{+}}+4{\text{SCN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Ag}{\left(\text{SCN}\right)}_{4}\right]}^{3-}$	1.2 $×$ 10¹⁰
${\text{Pb}}^{\text{2+}}+4{\text{I}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[{\text{PbI}}_{4}\right]}^{2-}$	3.0 $×$ 10⁴
${\text{Pt}}^{\text{2+}}+4{\text{Cl}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[{\text{PtCl}}_{4}\right]}^{2-}$	1 $×$ 10¹⁶
${\text{Cu}}^{\text{2+}}+4\text{CN}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Cu}{\left(\text{CN}\right)}_{4}\right]}^{2-}$	1.0 $×$ 10²⁵
${\text{Co}}^{\text{2+}}+4{\text{SCN}}^{\text{−}}\phantom{\rule{0.2em}{0ex}}⇌\phantom{\rule{0.2em}{0ex}}{\left[\text{Co}{\left(\text{SCN}\right)}_{4}\right]}^{2-}$	1 $×$ 10³

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